| Jornada 1 | 24/08/2014 | RAYO VALLEC. | 0 | ATLETICO MADRID | 0 |
| Jornada 2 | 31/08/2014 | DEPORTIVO | 2 | RAYO VALLEC. | 2 |
| Jornada 3 | 14/09/2014 | RAYO VALLEC. | 2 | ELCHE | 3 |
| Jornada 4 | 21/09/2014 | VILLARREAL | 4 | RAYO VALLEC. | 2 |
| Jornada 5 | 25/09/2014 | RAYO VALLEC. | 2 | ATHLETIC BILBAO | 1 |
| Jornada 6 | 28/09/2014 | LEVANTE | 0 | RAYO VALLEC. | 2 |
| Jornada 7 | 05/10/2014 | RAYO VALLEC. | 0 | FC BARCELONA | 2 |
| Jornada 8 | 19/10/2014 | GRANADA | 0 | RAYO VALLEC. | 1 |
| Jornada 9 | 26/10/2014 | MALAGA | 4 | RAYO VALLEC. | 0 |
| Jornada 10 | 02/11/2014 | RAYO VALLEC. | 2 | EIBAR | 3 |
| Jornada 11 | 09/11/2014 | REAL MADRID | 5 | RAYO VALLEC. | 1 |
| Jornada 12 | 23/11/2014 | RAYO VALLEC. | 1 | CELTA | 0 |
| Jornada 13 | 30/11/2014 | ALMERIA | 0 | RAYO VALLEC. | 1 |
| Jornada 14 | 07/12/2014 | RAYO VALLEC. | 0 | SEVILLA | 1 |
| Jornada 15 | 14/12/2014 | VALENCIA | 3 | RAYO VALLEC. | 0 |
| Jornada 16 | 21/12/2014 | RAYO VALLEC. | 1 | ESPANYOL | 3 |
| Jornada 17 | 04/01/2015 | GETAFE | 1 | RAYO VALLEC. | 2 |
| Jornada 18 | 11/01/2015 | RAYO VALLEC. | 0 | CORDOBA | 1 |
| Jornada 19 | 18/01/2015 | REAL SOCIEDAD | 0 | RAYO VALLEC. | 1 |
| Jornada 20 | 25/01/2015 | ATLETICO MADRID | 3 | RAYO VALLEC. | 1 |
| Jornada 21 | 01/02/2015 | RAYO VALLEC. | | DEPORTIVO | |
| Jornada 22 | 08/02/2015 | ELCHE | | RAYO VALLEC. | |
| Jornada 23 | 15/02/2015 | RAYO VALLEC. | | VILLARREAL | |
| Jornada 24 | 22/02/2015 | ATHLETIC BILBAO | | RAYO VALLEC. | |
| Jornada 25 | 01/03/2015 | RAYO VALLEC. | | LEVANTE | |
| Jornada 26 | 08/03/2015 | FC BARCELONA | | RAYO VALLEC. | |
| Jornada 27 | 15/03/2015 | RAYO VALLEC. | | GRANADA | |
| Jornada 28 | 22/03/2015 | RAYO VALLEC. | | MALAGA | |
| Jornada 29 | 05/04/2015 | EIBAR | | RAYO VALLEC. | |
| Jornada 30 | 09/04/2015 | RAYO VALLEC. | | REAL MADRID | |
| Jornada 31 | 12/04/2015 | CELTA | | RAYO VALLEC. | |
| Jornada 32 | 19/04/2015 | RAYO VALLEC. | | ALMERIA | |
| Jornada 33 | 26/04/2015 | SEVILLA | | RAYO VALLEC. | |
| Jornada 34 | 30/04/2015 | RAYO VALLEC. | | VALENCIA | |
| Jornada 35 | 03/05/2015 | ESPANYOL | | RAYO VALLEC. | |
| Jornada 36 | 10/05/2015 | RAYO VALLEC. | | GETAFE | |
| Jornada 37 | 17/05/2015 | CORDOBA | | RAYO VALLEC. | |
| Jornada 38 | 24/05/2015 | RAYO VALLEC. | | REAL SOCIEDAD | |